Decarboxylative substitution of β-keto acids to benzylic alcohols catalyzed by molecular iodine

被引：14
|
作者：
Han, Fuzhong [1 ]
Zhang, Xinxin [1 ]
Hu, Minggang [1 ]
Jia, Lina [1 ]
机构：
[1] Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 47期
基金：
中国国家自然科学基金;
关键词：
1,3-DICARBONYL COMPOUNDS; ARYLBORONIC ACIDS; BENZYLATION; ARENES; 1,4-ADDITION; CONSTRUCTION; ALLYLATION; ADDITIONS; ESTERS;
D O I：
10.1039/c5ob01730k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient method for molecular iodine catalyzed decarboxylative substitution of beta-keto acids with benzylic alcohols under mild conditions has been described and valuable alpha-functionalized ketones were obtained in good to excellent yields.
引用
收藏
页码：11466 / 11471
页数：6
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