Decarboxylative substitution of β-keto acids to benzylic alcohols catalyzed by molecular iodine

被引：14
|
作者：
Han, Fuzhong [1 ]
Zhang, Xinxin [1 ]
Hu, Minggang [1 ]
Jia, Lina [1 ]
机构：
[1] Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 47期
基金：
中国国家自然科学基金;
关键词：
1,3-DICARBONYL COMPOUNDS; ARYLBORONIC ACIDS; BENZYLATION; ARENES; 1,4-ADDITION; CONSTRUCTION; ALLYLATION; ADDITIONS; ESTERS;
D O I：
10.1039/c5ob01730k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient method for molecular iodine catalyzed decarboxylative substitution of beta-keto acids with benzylic alcohols under mild conditions has been described and valuable alpha-functionalized ketones were obtained in good to excellent yields.
引用
收藏
页码：11466 / 11471
页数：6
相关论文
共 50 条
  • [1] Ferric chloride-catalyzed decarboxylative alkylation of β-keto acids with benzylic alcohols
    Yang CuiFeng
    Shen Chen
    Li HaiHua
    Tian ShiKai
    CHINESE SCIENCE BULLETIN, 2012, 57 (19): : 2377 - 2381
  • [2] Molecular Iodine-Catalyzed N-Benzylic Sulfonamides C-N Bond Cleavage for the Decarboxylative Substitution of β-Keto Acids
    Jia, Lina
    Zhao, Jinyu
    Hu, Xiangping
    LETTERS IN ORGANIC CHEMISTRY, 2022, 19 (11) : 924 - 930
  • [3] Iodine-catalyzed nucleophilic substitution reactions of benzylic alcohols
    Srihari, Pabbaraja
    Bhunia, Dinesh C.
    Sreedhar, Pamu
    Yadav, Jhillu S.
    SYNLETT, 2008, (07) : 1045 - 1049
  • [4] Iodine-Catalyzed Borylation of Benzylic Alcohols
    Yin, Chunyu
    Luo, Lu
    Zhang, Hua
    ORGANIC LETTERS, 2023, 25 (10) : 1701 - 1705
  • [5] Copper-Catalyzed Enantioselective Decarboxylative Cyanation of Benzylic Acids Promoted by Hypervalent Iodine(III) Reagents
    Li, Zhaoxia
    Zhang, Guang'an
    Song, Yue
    Li, Miaomiao
    Li, Zhongxian
    Ding, Wei
    Wu, Junliang
    ORGANIC LETTERS, 2023, 25 (17) : 3023 - 3028
  • [6] Synthesis of Benzylic Alcohols by Decarboxylative Hydroxylation
    Yu, Qian
    Zhou, Donglin
    Liu, Yaoyue
    Huang, Xuejin
    Song, Chunlan
    Ma, Junjun
    Li, Jiakun
    ORGANIC LETTERS, 2023, 25 (01) : 47 - 52
  • [7] Iron catalyzed oxidation of benzylic alcohols to benzoic acids
    Stanje, B.
    Traar, P.
    Schachner, J. A.
    Belaj, F.
    Moesch-Zanetti, N. C.
    DALTON TRANSACTIONS, 2018, 47 (18) : 6412 - 6420
  • [8] Aerobic photocatalytic oxidation of activated benzylic and allylic alcohols to carbonyl compounds catalyzed by molecular iodine
    Farhadi, Saeid
    Zabardasti, Abedien
    Babazadeh, Zaynab
    TETRAHEDRON LETTERS, 2006, 47 (50) : 8953 - 8957
  • [9] Iodine-catalyzed N-alkylation of tosylhydrazones with benzylic alcohols
    P. Theerthagiri
    A. Lalitha
    Journal of the Iranian Chemical Society, 2013, 10 : 717 - 724
  • [10] Iodine-catalyzed N-alkylation of tosylhydrazones with benzylic alcohols
    Theerthagiri, P.
    Lalitha, A.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2013, 10 (04) : 717 - 724
12345