van der Waals Radii of Noble Gases

被引:53
|
作者
Vogt, Juergen [1 ]
Alvarez, Santiago [2 ,3 ]
机构
[1] Univ Ulm, D-89069 Ulm, Germany
[2] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[3] Univ Barcelona, Inst Quim Teor & Computac, E-08028 Barcelona, Spain
关键词
CRYSTAL-STRUCTURES; SPECTRA; SPECTROSCOPY; DATABASE; VOLUMES;
D O I
10.1021/ic501364h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Consistent van der Waals radii are deduced for Ne-Xe, based on the noble gas oxygen intermolecular distances found in gas phase structures. The set of radii proposed is shown to provide van der Waals distances for a wide variety of noble gas. element atom pairs that represent properly the distribution of distances both in the gas phase and in the solid state. Moreover, these radii show a smooth periodic trend down the group which is parallel to that shown by the halogens.
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页码:9260 / 9266
页数:7
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