The influence of ligands on the bonding mode of thiocyanate group in copper(II) complexes with polyamines

被引：0
|
作者：
Macaskova, L
Maslejova, A
Kabesova, M
Melnik, M
机构：
来源：
POLISH JOURNAL OF CHEMISTRY | 1996年 / 70卷 / 03期
关键词：
complexes; synthesis; optical spectra; magnetic susceptibility;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new series of compounds of general formula CuL(2)(NCS)X (where L = N,N'-dimethylethylenediamine (sym-Me(2)en), 1,3-diaminopropane (DAP) and N-aminopropylcyclohexylamine (ACHA) and X = CIO4-, NO3-, BF4-, SCN- has been prepared. Structural properties were characterized by spectral and magnetic measurements. The substitution of one NCS group in Cu(sym-Me(2)en)(2)(NCS)(2) and of one SCN group in Cu(DAP)(2)(SCN)(2) and Cu(ACHA)(2)(SCN)(2) for NO3-, ClO4- and BF4- anions leads to N-coordination of NCS group in these compounds.
引用
收藏
页码：284 / 287
页数：4
相关论文
共 50 条
  • [31] SOLID-STATE C-13 NMR CHARACTERIZATION OF THE BONDING MODE OF THE THIOCYANATE ION IN COPPER(I) COMPLEXES
    ZUMBULYADIS, N
    GYSLING, HJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (11) : 3246 - 3247
  • [32] Synthesis, Structure and Properties of Copper(II) Complex with Pyrazole Ligands and Thiocyanate
    Sun, Ying-Ji
    Zhao, Bin
    Shi, Wei
    Cheng, Peng
    Yan, Shi-Ping
    Shen, Pan-Wen
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 2001, 22 (10 SUPPL.): : 31 - 32
  • [33] Synthesis, Structure and Properties of Copper(II) Complex with Pyrazole Ligands and Thiocyanate
    Sun Ying-Ji
    Zhao Bin
    Shi Wei
    Cheng Peng
    Yan Shi-Ping
    Shen Pan-Wen
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2001, 22 : 29 - 32
  • [34] COPPER(II) AND COPPER(I) COMPLEXES OF TWEEZER LIGANDS - INFLUENCE OF SUBSTITUENTS ON THE TRANSPORT OF COPPER(II) IONS ACROSS LIQUID MEMBRANES
    AMEERUNISHA, S
    ZACHARIAS, PS
    POLYHEDRON, 1994, 13 (15-16) : 2327 - 2332
  • [35] Structural diversity and magnetic properties of thiocyanate copper(II) complexes
    Machura, B.
    Switlicka, A.
    Mrozinski, J.
    Kalinska, B.
    Kruszynski, R.
    POLYHEDRON, 2013, 52 : 1276 - 1286
  • [36] KINETICS OF REPLACEMENT OF AMINOCARBOXYLATES BY MACROCYCLIC POLYAMINES IN COPPER(II) COMPLEXES
    KODAMA, M
    KIMURA, E
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (03): : 247 - 253
  • [37] STABLE ANIONIC COMPLEXES OF COPPER(II) WITH CYANIDE, IODIDE AND THIOCYANATE
    DANI, CM
    DAS, AK
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1986, 25 (01): : 78 - 79
  • [38] COORDINATION OF THIOCYANATE IN TETRAAMINE AND DIIMINE DIAMINE COMPLEXES OF COPPER(II)
    WU, DT
    CHUNG, CS
    INORGANIC CHEMISTRY, 1986, 25 (20) : 3584 - 3587
  • [39] MANGANESE(II) CHLORIDE AND THIOCYANATE COMPLEXES WITH SOME POTENTIALLY BIDENTATE LIGANDS
    AHUJA, IS
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1983, 22 (03): : 262 - 264
  • [40] BINUCLEAR COPPER(II) COMPLEXES IN WHICH OTHER COPPER(II) COMPLEXES ARE COORDINATED AS BIDENTATE LIGANDS
    OJIMA, H
    NONOYAMA, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1973, 401 (02): : 195 - 206
12345