Enantioselective Diels-Alder reaction of anthracene by chiral tritylium catalysis

被引：18

作者：

Zhang, Qichao ^{[1
]}

Lv, Jian ^{[1
,2
]}

Luo, Sanzhong ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China

[2] Qingdao Univ Sci & Technol, State Key Lab Base Ecochem Engn, Coll Chem & Mol Engn, Qingdao 266042, Shandong, Peoples R China

[3] Tsinghua Univ, Dept Chem, CBMS, Beijing 100084, Peoples R China

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 15卷

关键词：

anthracene; carbocation catalysis; Diels-Alder reaction; Fe(III)-based phosphate anion; tritylium salt; WEAKLY COORDINATING ANIONS; LEWIS-ACID CATALYSTS; STEREOSPECIFIC OLEFIN POLYMERIZATION; CARBOCATIONS; COCATALYSTS; NB; AL;

D O I：

10.3762/bjoc.15.129

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantioselective Diels-Alder reaction of anthracene.

引用

页码：1304 / 1312

页数：9

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