A cobalt (II) complex based on antipyrine derived schiff base as colorimetric sensor for Fe3+ ion

被引：0
|
作者：
Zhang, Xiao-Yong [1 ]
Ma, Xue-Lin [1 ]
Gao, Jun-Fang [1 ]
Wang, Mei-Rong [1 ]
Zhang, Yu-Heng [1 ]
Yong, Sheng-Li [1 ]
机构：
[1] Baotou Teachers Coll, Dept Chem, Baotou 014030, Peoples R China
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2022年 / 99卷 / 04期
基金：
中国国家自然科学基金;
关键词：
Co (II) complex; Sensor; Sensing mechanism; Fe3+ ion; FLUORESCENT SENSOR; LUMINESCENT SENSOR; HIGH SELECTIVITY; RECOGNITION; POLYMER; SENSITIVITY; CHEMOSENSOR; FRAMEWORK; PROBE; CU2+;
D O I：
10.1016/j.jics.2022.100394
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel complex [Co(NO3)(2)(APTY)(2)H2O] (1) is synthesized based on 1,5-dimethyl-2-phenyl-4-{[(1E)-pyridine-4-ylmethylene]amino}-1,2-dihydro-3H-pyrazol-3-one) antipyrine (APTY) and the structure of complex (1) is characterized via PXRD, SEM, FTIR and X-ray single crystal diffraction technique. It is found that the complex (1) has a good response to Fe3+ ion with colorimetric yellow change. In addition, we demonstrate that the sensing mechanism of complex (1) could is due to the disruption of complex (1) framework and the formation of complex Fe-APTY. The stability, rapid response and low detection limit enable this complex (1) to be a good Fe3+ ion chemical sensor for biological and environmental sensing applications.
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页数：8
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