Di-μ-benzoato-κ3O,O′:O;κ3O:O,O′-bis[(acetato-κO)(1,10-phenanthroline-κ2N,N′)lead(II)] dihydrate

被引：2
|
作者：
Gao, Junli [1 ]
Xuan, Xiaopeng [1 ]
机构：
[1] Henan Normal Univ, Dept Chem, Xinxiang 453007, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809025896
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Pb-2(CH3COO)(2)(C7H5O2)(2)(C12H8N2)(2)]center dot-2H(2)O, consists of dimeric units built up around a crystallographic centre of symmetry and two non-coordinating water molecules. Each Pb-II unit is six-coordinated by a bidentate 1,10-phenanthroline (phen) ligand, a monodentate acetate anion and a bidentate benzoate anion, which also acts as a bridge linking the two Pb-II atoms. The crystal packing is stabilized by O-H center dot center dot center dot O hydrogen bonds and by pi-pi interactions between the phen rings of neighboring molecules, with a centroid-centroid distance of 3.577 (3) angstrom.
引用
收藏
页码：M900 / U731
页数：13
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