One Novel Mn(II) Complex with 1-Substituted-1H-1,2,3-triazole-4-carboxylic Acid: Crystal Structure, Fluorescence and Hirshfeld Surface Analysis

被引：4
|
作者：
Zhao Hong [1 ]
Zhu Yu-Qing [1 ]
Feng Chao [1 ]
机构：
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Mn(II) complex; crystal structure; supramolecular structure; Hirshfeld surface; HYDROTHERMAL SYNTHESES; COORDINATION POLYMERS; ZN(II) COMPLEXES; 1,2,3-TRIAZOLE; LUMINESCENCE;
D O I：
10.14102/j.cnki.0254-5861.2011-1196
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of one novel Mn(II) complex, [Mn(pmta)(3)](2)[Mn(H2O)(6)]center dot 4H(2)O (1), is reported (Hpmta = 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid). In the title compound, the asymmetric unit consists of a [Mn(pmta)(3)](-) anion, half [Mn(H2O)(6)](2+) counter cation and two lattice H2O molecules, and the intra-and intermolecular hydrogen bonds connect the complex into a supramolecular structure. The liquid-state fluorescence spectra of complex 1 have been determined. Hirshfeld surface analysis was also studied. The main intermolecular interactions in the complex are O center dot center dot center dot H and H center dot center dot center dot H contacts.
引用
收藏
页码：66 / 72
页数：7
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