Modulating high-energy visible light absorption to attain neutral-state black electrochromic polymers

被引:76
|
作者
Neo, Wei Teng [1 ,2 ]
Cho, Ching Mui [1 ]
Shi, Zugui [1 ]
Chua, Soo-Jin [1 ,3 ]
Xu, Jianwei [1 ,4 ]
机构
[1] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore
[2] Natl Univ Singapore, NUS Grad Sch Integrat Sci & Engn, Singapore 117456, Singapore
[3] Natl Univ Singapore, Dept Elect & Comp Engn, Singapore 117583, Singapore
[4] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
关键词
DONOR-ACCEPTOR COPOLYMERS; DIOXYTHIOPHENE; PERFORMANCE; RED;
D O I
10.1039/c5tc02883c
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Neutral-state black diketopyrrolopyrrole (DPP)-based conjugated polymers with the colour channels a*from -3 to 0 and b* from -2 to -7 are achieved by incorporating an additional donor segment - dialkoxythiophene (DalkOT), which leads to the enhancement in blue-wavelength absorption. The polymers display black-to-transmissive grey electrochromic switching with good redox stability.
引用
收藏
页码:28 / 32
页数:5
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