One-pot conversion of olefins to carbonyl compounds by hydroboration NMO-TPAP oxidation

被引:22
|
作者
Yates, MH
机构
[1] Department of Chemistry, Rice University, Houston, TX 77005
基金
美国国家科学基金会; 美国国家卫生研究院;
关键词
D O I
10.1016/S0040-4039(97)00476-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient method to oxidize an olefin to the less substituted carbonyl compound is described This new methodology utilizes borane dimethyl sulfide followed by tetrapropylammonium perruthenate N-methylmorpholine N-oxide to oxidize the resulting alkylborane. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:2813 / 2816
页数:4
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