Copper(II)-catalyzed O-phenylation of tertiary alcohols with organobismuth(V) reagents

被引：24
|
作者：
Ikegai, Kazuhiro
Fukumoto, Kentarou
Mukaiyama, Teruaki
机构：
[1] Kitasato Inst, Ctr Basic Res, Kita Ku, Tokyo 1140003, Japan
[2] Astellas Pharma Inc, Miyukigaoka Res Ctr, Tsukuba, Ibaraki 3058585, Japan
[3] Kitasato Univ, Kitasato Inst Life Sci, Minato Ku, Tokyo 1088641, Japan
来源：
CHEMISTRY LETTERS | 2006年 / 35卷 / 06期
关键词：
D O I：
10.1246/cl.2006.612
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new method for the Cu(OAc)(2)-catalyzed phenylation of tertiary alcohols under mild basic conditions is described. Triphenylbismuth(V) diacetate and tetraphenylbismuth reagents undergo cross-coupling reactions with alpha-hydroxycarbonyl compouds efficiently. For non-chelating tertiary alcohols, tetraphenylbismuth fluoride is found suitable as a phenyl donor.
引用
收藏
页码：612 / 613
页数：2
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