Radical-mediated thiodesulfonylation of the vinyl sulfones: access to (α-fluoro)vinyl sulfides

被引：33

作者：

Sacasa, Pablo R. ^{[1
]}

Zayas, Jessica ^{[1
]}

Wnuk, Stanislaw F. ^{[1
]}

机构：

[1] Florida Int Univ, Dept Chem & Biochem, Miami, FL 33199 USA

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 38期

关键词：

Fluoroalkenes; Radical reactions; Vinyl sulfides; alpha-Fluoro vinyl sulfides; Vinyl sulfones; CROSS-COUPLING REACTION; STEREOSELECTIVE-SYNTHESIS; STEREOSPECIFIC METHOD; HALIDES; HYDROTHIOLATION; INACTIVATION; OLEFINS; ALKYNES; THIOLS; MILD;

D O I：

10.1016/j.tetlet.2009.07.063

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical-mediated thiodesulfonylation of the vinyl and (alpha-fluoro)vinyl sulfones, derived from aldehydes and ketones, with aryl thiols in organic or aqueous medium provided access to vinyl and (a-fluoro)vinyl sulfides. The vinyl sulfides were formed predominantly with E stereochemistry independent of the stereochemistry of the starting vinyl sulfones. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：5424 / 5427

页数：4

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