One-electron oxidation of metal enolates and metal phenolates

被引：34

作者：

Schmittel, M ^{[1
]}

Haeuseler, A ^{[1
]}

机构：

[1] Univ Siegen, D-57068 Siegen, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 661卷 / 1-2期

关键词：

metal enolate; metal phenolate; radical cation; bond cleavage; stereoselectivity; kinetics;

D O I：

10.1016/S0022-328X(02)01823-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure and reactivity of a large number of metal enolates/metal phenolates and their radical cations is analyzed from both a preparative and mechanistic point of view. Special attention is given to the M-O bond cleavage and the C-C coupling on the stage of the radical cations. The insight obtained allowed to devise a novel selective oxidative coupling of enolates and phenolates through an intramolecular variant. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：169 / 179

页数：11

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