Nickel-Catalyzed C-H Bond Functionalization Utilizing an N,N′-Bidentate Directing Group

被引:24
|
作者
Chatani, Naoto [1 ]
机构
[1] Osaka Univ, Dept Appl Chem, Suita, Osaka 5650871, Japan
关键词
C-H activation; C-H functionalization; Chelation assistance; Nickel; UNACTIVATED C(SP(3))-H BONDS; AROMATIC AMIDES; OXIDATIVE CYCLOADDITION; COUPLING REACTIONS; C(SP(2))-H BONDS; DIRECT ARYLATION; ACTIVATION; ALKYLATION; BENZAMIDES; PALLADIUM;
D O I
10.1007/3418_2015_117
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review discusses the use of nickel catalysts and N,N'-bidentate directing groups, such as 2-pyridinylmethylamine, 8-aminoquinoline, and derivatives thereof, which constitute a powerful combination for the chelation-assisted functionalization of C-H bonds.
引用
收藏
页码:19 / 46
页数:28
相关论文
共 50 条
  • [31] Nickel-Catalyzed Aromatic C–H Functionalization
    Junichiro Yamaguchi
    Kei Muto
    Kenichiro Itami
    Topics in Current Chemistry, 2016, 374
  • [32] Recent advances in nickel-catalyzed C-H bond functionalized reactions
    Cai, Xiao-hua
    Xie, Bing
    ARKIVOC, 2015, : 184 - 211
  • [33] Use of the Hydantoin Directing Group in Ruthenium(II)-Catalyzed C-H Functionalization
    Leitch, Jamie A.
    Cook, Hans P.
    Bhonoah, Yunas
    Frost, Christopher G.
    JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (20): : 10081 - 10087
  • [34] Nickel-Catalyzed C-H Functionalization Using A Non-directed Strategy
    Khake, Shrikant M.
    Chatani, Naoto
    CHEM, 2020, 6 (05): : 1056 - 1081
  • [35] The Transient Directing Group Strategy: A New Trend in Transition-Metal-Catalyzed C-H Bond Functionalization
    Zhao, Qun
    Poisson, Thomas
    Pannecoucke, Xavier
    Besset, Tatiana
    SYNTHESIS-STUTTGART, 2017, 49 (21): : 4808 - 4826
  • [36] Nickel-catalyzed C-H bond trifluoromethylation of 8-aminoquinoline derivatives by acyl-directed functionalization
    Liu, Xiaochong
    Mao, Guijie
    Qiao, Jingyi
    Xu, Chunzhao
    Liu, Hao
    Ma, Junjie
    Sun, Zhizhong
    Chu, Wenyi
    ORGANIC CHEMISTRY FRONTIERS, 2019, 6 (08) : 1189 - 1193
  • [37] Ruthenium-Catalyzed Oxidative C-H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group
    Li, Bin
    Ma, Jianfeng
    Wang, Nuancheng
    Feng, Huiliang
    Xu, Shansheng
    Wang, Baiquan
    ORGANIC LETTERS, 2012, 14 (03) : 736 - 739
  • [38] N-Amino-7-azaindole as the N,N'-Bidentate Directing Group: Ruthenium-Catalyzed Oxidative Annulation of N-(7-Azaindole)benzamides with Alkynes via C-H Bond Activation
    Sagara, Prateep Singh
    Siril, Prem Felix
    Ravikumar, Ponneri Chandrababu
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (19): : 12314 - 12323
  • [39] Copper-Catalyzed or -Mediated C-H Bond Functionalizations Assisted by Bidentate Directing Groups
    Liu, Jidan
    Chen, Guoshu
    Tan, Ze
    ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (08) : 1174 - 1194
  • [40] Nickel catalyzed alkylation of N-aromatic heterocycles with Grignard reagents through direct C-H bond functionalization
    Xin, Peng-Yang
    Niu, Hong-Ying
    Qu, Gui-Rong
    Ding, Rui-Fang
    Guo, Hai-Ming
    CHEMICAL COMMUNICATIONS, 2012, 48 (53) : 6717 - 6719