Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+[Hg2I6]2- and {[2,6-(OMe)2C6H3]3SbMe}2+[HgI4]2-•DMSO: Synthesis and Structure

被引：5
|
作者：
Egorova, I., V [1 ]
Zhidkov, V. V. [1 ]
Grinishak, I. P. [1 ]
Bagryanskaya, I. Yu [2 ,3 ]
Pervukhina, N., V [3 ,4 ]
Eltsov, I., V [3 ]
Kurat'eva, N., V [3 ,4 ]
机构：
[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia
[2] Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
[3] Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia
[4] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 64卷 / 01期
关键词：
tris(2,6-dimethoxyphenyl) antimony; ethyl iodoacetate; 1,4-diiodobutane; tris(2,6-dimethoxyphenyl) (ethoxycarbonylmethyl) antimony iodide; tris(2,6-dimethoxyphenyl) methyl antimony iodide; mercury diiodide; X-ray diffraction analysis; nuclear magnetic resonance; DONOR-ACCEPTOR COMPLEXES; ORGANO-VERBINDUNGEN; DERIVATIVES;
D O I：
10.1134/S0036023619010078
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
It has been established that ethyl iodoacelate and 1,4-diiodobutane alkylate triarylantimony Ar3Sb with the formation of [Ar3SbCH2C(O)OEt]I-+(-) and [Ar3Sb(CH2)(4)I]I-+(-), [Ar3Sb(CH2)(4)SbAr3]I-2+(2)- where Ar = 2,6-(OMe)(2)C6H3. The complexes [Ar3SbCH2C(O)OEt](2)(+)[Hg2I6](2) and [Ar3SbMe](2)(+)[HgI4](2) center dot DMSO have been synthesized by the reaction of [Ar3SbCH2C(O)OEt]I-+(-) and [Ar3SbMe]I-+(-) with mercury diiodide and studied by X-ray diffraction. The antimony and iodine atoms have a distorted tetrahedral coordination. The CSbC and IHgI angles are ranged within 103.28(14)degrees-116.68(14)degrees, 103.7(4)degrees-115.5(4)degrees and 98.122(9)degrees 125.590(12)degrees, 102.66(2)degrees-115.64(2)degrees, respectively.
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页码：28 / 35
页数：8
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