Ruthenium complexes of tetradentate bipyridine ligands: highly efficient catalysts for the hydrogenation of carboxylic esters and lactones

被引：80
|
作者：
Li, Wei [1 ]
Xie, Jian-Hua
Yuan, Ming-Lei
Zhou, Qi-Lin
机构：
[1] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn, State Key Lab, Tianjin 300071, Peoples R China
来源：
GREEN CHEMISTRY | 2014年 / 16卷 / 09期
基金：
中国国家自然科学基金;
关键词：
ASYMMETRIC HYDROGENATION; ALCOHOLS; ACID; BIOMASS; COOPERATION; CARBONATES; METHANOL; MILD; CO2;
D O I：
10.1039/c4gc00835a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new type of readily available, air-stable ruthenium complex of tetradentate bipyridine ligands has been developed. These complexes displayed exceptional efficiency for the hydrogenation of aromatic and aliphatic carboxylic esters and lactones at as low as 10 ppm catalyst loading under very mild conditions.
引用
收藏
页码：4081 / 4085
页数：5
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