Ceramic-monolith-supported La0.8Ce0.2MnO3 catalysts for toluene oxidation

被引:9
|
作者
Zang, Meng [1 ]
Zhao, Chaocheng [1 ,2 ]
Wang, Yongqiang [1 ,2 ]
Chen, Shuiquan [1 ]
Liu, Xin [1 ]
Zhang, Yusheng [1 ]
机构
[1] China Univ Petr East China, Coll Chem Engn, Qingdao 266580, Shandong, Peoples R China
[2] China Univ Petr East China, State Key Lab Petr Pollut Control, Qingdao 266580, Shandong, Peoples R China
关键词
Ceramics; Perovskite; Composite materials; Oxidation; Toluene; PEROVSKITES; COMBUSTION;
D O I
10.1016/j.matlet.2019.05.135
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of ceramic monolith (cordierite, corundum and mullite-cordierite) supported La0.8Ce0.2MnO3 catalysts for toluene oxidation were prepared and characterized to study the structure-activity relationship. The effects of loading and support were investigated by discussing the specific surface area, reduction ability, oxygen vacancies, and toluene oxidation efficiency. Finally, the optimum catalyst was obtained; when loading of La0.8Ce0.2MnO3 was 15 wt% and the carrier was cordierite, the catalyst exhibited the largest specific surface area (21.4 m(2).g-(1)) and best toluene conversion (T-50 = 167 degrees C, T-90 = 273 degrees C). (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:196 / 200
页数:5
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