Structure determination of unusual mixed-ligand complexes [LoMeInTp]X (X = [InCl4]-, [PF6]-) in solution by 2D 1H NOESY NMR spectroscopy

被引：0
|
作者：
Kläui, W [1 ]
Liedtke, N [1 ]
Peters, W [1 ]
机构：
[1] Univ Dusseldorf, Inst Anorgan Chem & Strukturchem 1, D-40225 Dusseldorf, Germany
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 1999年 / 37卷 / 12期
关键词：
NMR; H-1; P-31; NOESY; mixed-ligand complexes; indium; tris(pyrazol-1-yl)borate; (cyclopentadienyl)tris(dimethylphosphito-P)cobaltate(1-);
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Indium complexes [L(OMe)InTp][InCl4](4) and [L(OMe)InTp][PF6] (5) containing the tripodal nitrogen ligand Tp(-){Tp(-) = hydrotris(pyrazol-2-yl)borate, [HB(pz)(3)](-)} and the tripodal oxygen ligand L-OMe(-)(L-OMe(-) = (cyclopentadienyl)tris(dimethylphosphito-P)cobaltate(1-), [eta(5)-(C5H5)Co{P(O)R-2}(3)](-)) were synthesized in high yields. Compounds 4 and 5 are the first complexes with a fac-N3O3 coordination bearing both Klaui's and Trofimenko's tripodal ligands. Their structure in solution was determined unambiguously by 2D H-1 NOESY NMR spectroscopy. Copyright (C) 1999 John Wiley & Sons, Ltd.
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页码：867 / 870
页数：4
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