AFM analysis of initial stage of reaction between calcite and phosphate

被引:27
|
作者
Kamiya, M
Hatta, J
Shimada, E
Ikuma, Y
Yoshimura, M
Monma, H
机构
[1] Kanagawa Inst Technol, Atsugi, Kanagawa 2430292, Japan
[2] Tokyo Inst Technol, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[3] Kogakuin Univ, Hachioji, Tokyo 1920015, Japan
关键词
calcite; atomic force microscopy (AFM); carbonate-containing hydroxyapatite;
D O I
10.1016/j.mseb.2004.05.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A calcite surface reacted with phosphoric acid or phosphate in the initial stage was analyzed under an atomic force microscopy (AFM). The cleaved calcite was immersed in phosphoric acid or diammonium hydrogenphosphate under various conditions. The calcite dissolved upon immersion in phosphoric acid and many pits, oriented in a particular direction, were observed on the calcite surface. When the calcite was immersed in diammonium hydrogenphosphate, reaction products, also aligned in a particular direction, were observed on the calcite surface. X-ray diffraction analysis revealed that these products are carbonate-containing hydroxyapatite. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:226 / 231
页数:6
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