Dinuclear lanthanide(III)/zinc(II) complexes with methyl 2-pyridyl ketone oxime

被引：23

作者：

Anastasiadis, Nikolaos C. ^{[1
,2
]}

Polyzou, Christina D. ^{[1
,2
]}

Kostakis, George E. ^{[1
,3
]}

Bekiari, Vlasoula ^{[4
]}

Lan, Yanhua ^{[5
]}

Perlepes, Spyros P. ^{[2
]}

Konidaris, Konstantis F. ^{[1
]}

Powell, Annie K. ^{[1
,5
]}

机构：

[1] Karlsruhe Inst Technol, Inst Nanotechnol, D-76344 Eggenstein Leopoldshafen, Germany

[2] Univ Patras, Dept Chem, GR-26504 Patras, Greece

[3] Univ Sussex, Dept Chem, Sch Life Sci, Brighton BN1 9QJ, E Sussex, England

[4] Technol Educ Inst Western Greece, Dept Aquaculture, GR-30200 Mesolongion, Greece

[5] Karlsruhe Inst Technol, Inst Inorgan Chem, D-76131 Karlsruhe, Germany

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 46期

关键词：

SINGLE-MOLECULE-MAGNET; ION-MAGNET; DI-2-PYRIDYL KETONE; LANTHANIDE IONS; LUMINESCENT; ZN; RELAXATION; EMISSION; CLUSTERS; BEHAVIOR;

D O I：

10.1039/c5dt03663a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first use of methyl 2-pyridyl ketone oxime (mpkoH) in zinc(II)/lanthanide(III) chemistry leads to the [ZnLn(mpko)(3)(mpkoH)(3)](ClO4)(2) and [ZnLn(NO3)(2)(mpko)(3)(mpkoH)] families of dinuclear Zn(II)Ln(III) complexes displaying blue-green, ligand-based photoluminescence; the (ZnDyIII)-Dy-II compound shows field-induced relaxation of magnetization.

引用

页码：19791 / 19795

页数：5

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