Pd-Catalyzed Hydrogen-Transfer Reactions from Alcohols to C=C, C=O, and C=N Bonds

被引：69

作者：

Muzart, Jacques ^{[1
]}

机构：

[1] Univ Reims, Inst Chim Mol Reims, UMR CNRS 7312, UFR Sci Exactes & Naturelles, F-51687 Reims 2, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 2015卷 / 26期

关键词：

Homogeneous catalysis; Palladium; Hydrogen transfer; C-C coupling; C-O coupling; C-N coupling; Alcohols; ASYMMETRIC TRANSFER HYDROGENATION; SELECTIVE ALPHA-ALKYLATION; AEROBIC DEHYDROGENATION; N-ALKYLATION; PALLADIUM CATALYST; CARBONYL-COMPOUNDS; CONJUGATE REDUCTION; MECHANISTIC ASPECTS; TERMINAL ALKENES; ALLYLIC ALCOHOLS;

D O I：

10.1002/ejoc.201500401

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review covers Pd-catalyzed abstracting and borrowing hydrogen transfers from alcohols to C=C, C=O, and C=N bonds. An abstracting hydrogen transfer implies a reaction in which an alcohol serves only as a hydrogen atom source, whereas in a borrowing hydrogen transfer the alcohol is part of the final product. Both transfer types involve a palladium monohydride or palladium dihydride, and are implicated in a variety of useful and safe one-pot reactions such as the formation, with low quantities of waste material, of C-C, C-O, and C-N bonds. Plausible mechanisms are, as far as possible, provided.

引用

页码：5693 / 5707

页数：15

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