Hybrid polymer particles by tandem ring-opening metathesis and atom transfer radical polymerizations in aqueous miniemulsion

被引：24
|
作者：
Quemener, Damien [1 ]
Bousquet, Antoine [1 ]
Heroguez, Valerie [1 ]
Gnanou, Yves [1 ]
机构：
[1] ENSCPB, Lab Chim Polymeres Organ, F-33607 Pessac, France
来源：
MACROMOLECULES | 2006年 / 39卷 / 17期
关键词：
D O I：
10.1021/ma061118o
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
One-pot synthesis of three types of particles obtained through simultaneous ROMP (ring-opening metathesis polymerization) and ATRP (atom transfer radical polymerization) carried out in aqueous dispersed medium was investigated. Polymerizations of NB (norbornene) by ROMP and of MMA (methyl methacrylate) by ATRP could be carried out simultaneously in the presence of purposely designed novel water-soluble ruthenium complexes leading to three types of hybrid particles filled with blends of homopolymers and graft and starlike copolymers. The conversion of both the NB and MMA vs polymerization times was monitored by gas chromatography. The SEC analysis of an aliquot reveals the formation of only one population of polymer chains indicative of the formation of the copolymers. The results confirm very good stability of both the monomer mini-emulsions and particles formed.
引用
收藏
页码：5589 / 5591
页数：3
相关论文
共 50 条
  • [21] CONTROLLED RING-OPENING METATHESIS POLYMERIZATIONS WITH WELL-DEFINED CATALYSTS
    SCHROCK, RR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 196 : 13 - POLY
  • [22] CONTROLLED RING-OPENING METATHESIS POLYMERIZATIONS WITH WELL-DEFINED CATALYSTS
    SCHROCK, RR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 476 - INOR
  • [23] CONTROLLED RING-OPENING METATHESIS POLYMERIZATIONS WITH WELL-DEFINED CATALYSTS
    SCHROCK, RR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 21 - PMSE
  • [24] Remote Control Grubbs Catalysts That Modulate Ring-Opening Metathesis Polymerizations
    Teator, Aaron J.
    Bielawski, Christopher W.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2017, 55 (18) : 2949 - 2960
  • [25] Entropy-driven ring-opening olefin metathesis polymerizations of macrocycles
    Xue, Zheng
    Mayer, Michael F.
    SOFT MATTER, 2009, 5 (23) : 4600 - 4611
  • [26] AQUEOUS RING-OPENING METATHESIS POLYMERIZATIONS OF HETEROPOLYCYCLIC CARBOXYLIC-ACIDS WITH TRANSITION-METAL CHLORIDES
    FEAST, WJ
    HARRISON, DB
    POLYMER, 1991, 32 (03) : 558 - 563
  • [27] Ring-Opening Metathesis Polymerization in Miniemulsion Using a TEGylated Ruthenium-Based Metathesis Catalyst
    Zhu, Chunyang
    Wu, Xiaowei
    Zenkina, Olena
    Zamora, Matthew T.
    Moffat, Karen
    Crudden, Cathleen M.
    Cunningham, Michael F.
    MACROMOLECULES, 2018, 51 (22) : 9088 - 9096
  • [28] Synthesis of latex particles by ring-opening metathesis polymerization
    Quémener, D
    Chemtob, A
    Héroguez, V
    Gnanou, Y
    POLYMER, 2005, 46 (04) : 1067 - 1075
  • [29] Ring-opening metathesis of cyclopropenes for polymer sequence control
    Elling, Benjamin
    Xia, Yan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [30] Synthesis of an electrophilic polymer by ring-opening metathesis polymerization
    Larsen, CA
    Taylor, EL
    Lambert, JN
    Chiefari, JA
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2002, 55 (04) : 245 - 248
12345