Lutidine/B(C6F5)3: At the Boundary of Classical and Frustrated Lewis Pair Reactivity

被引：288

作者：

Geier, Stephen J. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 10期

基金：

加拿大自然科学与工程研究理事会;

关键词：

HETEROLYTIC DIHYDROGEN ACTIVATION; FREE CATALYTIC-HYDROGENATION; METAL-FREE; BORANE; PHOSPHINES; CARBENE; IMINES; H-2;

D O I：

10.1021/ja900572x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Classical Lewis acid-base adducts, previously thought to be unreactive, can provide access to the unique reactivity of frustrated Lewis pairs. This was demonstrated with a mixture of 2,6-lutidine and B(C6F5)(3) where an equilibrium affords the adduct and yet also effects the heterolytic activation of H-2 and the ring opening of THF.

引用

页码：3476 / +

页数：3

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