Leaching characteristics of ion-adsorption type rare earths ore with magnesium sulfate

被引:118
|
作者
Xiao, Yan-fei [1 ,2 ]
Chen, Ying-ying [3 ]
Feng, Zong-yu [1 ,2 ]
Huang, Xiao-wei [1 ,2 ]
Huang, Li [1 ,2 ]
Long, Zhi-qi [1 ,2 ]
Cui, Da-li [1 ,2 ]
机构
[1] Gen Res Inst Nonferrous Met, Natl Engn Res Ctr Rare Earth Mat, Beijing 100088, Peoples R China
[2] GRIREM Adv Mat Co Ltd, Beijing 100088, Peoples R China
[3] China Univ Petr, Sch Chem Engn, Beijing 102200, Peoples R China
关键词
rare earth; leaching agent; kinetics; magnesium sulfate; ion-adsorption type rare earths ore; KINETICS; RECOVERY;
D O I
10.1016/S1003-6326(15)64022-5
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Magnesium sulfate was proposed to be leaching agent to deal with the ion-adsorption type rare earths ore to reduce or even eliminate ammonia-nitrogen emissions. The effects of temperature, particle size and stirring speed on rare earth leaching process and the leaching behaviors of the single rare earth element were investigated in order to reveal the rare earth leaching characteristics. Besides, the comparison of leaching effects between magnesium sulfate and ammonium sulfate was also studied. The results showed that the rare earth leaching process could be well described with inner diffusion control model and the apparent activation energy was 9.48 kJ/mol. The leaching behaviors of the single rare earth element were brought into correspondence with rare earths. Moreover, when the concentration of leaching agent was 0.20 mol/L, the rare earth leaching efficiency could all reach above 95% and the leaching efficiency of aluminum impurities could be restrained by 10% using magnesium sulfate compared with ammonium sulfate.
引用
收藏
页码:3784 / 3790
页数:7
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