Origin of the Excellent Performance of Ru on Nitrogen-Doped Carbon Nanofibers for CO2 Hydrogenation to CH4

被引：32

作者：

Roldan, Laura ^{[1
]}

Marco, Yanila ^{[1
]}

Garcia-Bordeje, Enrique ^{[1
]}

机构：

[1] CSIC, ICB, Inst Carboquim, Dept Chem Proc & Nanotechnol, Miguel Luesma Castan 4, Zaragoza 50018, Spain

来源：

CHEMSUSCHEM | 2017年 / 10卷 / 06期

关键词：

carbon; carbon dioxide; heterogeneous catalysis; methanation; ruthenium; METHANATION ACTIVITY; POROUS CARBONS; HETEROGENEOUS CATALYSIS; SURFACE-CHEMISTRY; DIOXIDE REDUCTION; ACTIVATED CARBONS; ADSORPTION; CAPTURE; NANOPARTICLES; SUPPORT;

D O I：

10.1002/cssc.201601217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon materials have rarely been used as support for CO2 methanation, which is usually carried out using catalysts supported on metal oxides. Here, it is shown that Ru nanoparticles supported on nitrogen-doped carbon nanofibers (NCNF) provide competitive CH4 production rate and stability compared to Al2O3-supported catalysts. Contrary to the general belief about the inert nature of carbon supports, it is demonstrated that NCNF is a non-innocent spectator in CO2 methanation due to its ability to store a high amount of COad reaction intermediates. This explains the excellent catalytic behaviour afforded by this unconventional catalyst support.

引用

页码：1139 / 1144

页数：6

共 50 条

[41] Ultrafast synthesis of SAPO-17 zeolites with excellent CO2/N2 and CO2/CH4 separation performance
Wang, Chaoran
Li, Xiao
Liu, Shiyue
Wang, Tingting
Liu, Puxu
Song, Xiaowei
Liang, Zhiqiang
INORGANIC CHEMISTRY FRONTIERS, 2023, 10 (15) : 4519 - 4525
[42] Nitrogen-doped Carbon Catalyst by Ultrasonic for Electrocatalytic CO2 Reduction
Liu, Jianfeng
Wang, Ting
Zhang, Zhenhai
Ning, Kai
Yin, Shibin
Yuan, Binxia
POLISH JOURNAL OF CHEMICAL TECHNOLOGY, 2020, 22 (03) : 24 - 28
[43] Nitrogen-doped mesoporous carbon supported CuSb for electroreduction of CO2
Hou, Yue
Jiang, Cheng-Jie
Wang, Ying
Zhu, Jing-Wei
Lu, Jia-Xing
Wang, Huan
RSC ADVANCES, 2022, 12 (21) : 12997 - 13002
[44] Harnessing the Synergy of Fe and Co with Carbon Nanofibers for Enhanced CO2 Hydrogenation Performance
Arizapana, Kevin
Schossig, John
Wildy, Michael
Weber, Daniel
Gandotra, Akash
Jayaraman, Sumedha
Wei, Wanying
Xu, Kai
Yu, Lei
Mugweru, Amos M.
Mantawy, Islam
Zhang, Cheng
Lu, Ping
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2024, 12 (05) : 1868 - 1883
[45] Nitrogen-doped mesoporous carbon supported FeCu bimetallic catalyst and its CO hydrogenation performance
Li, Zhi-Wen
Chen, Cong-Biao
Wang, Jun-Gang
Lin, Ming-Gui
Hou, Bo
Jia, Li-Tao
Li, De-Bao
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2019, 47 (06): : 709 - 717
[46] Nitrogen and sulfur co-doped microporous carbon prepared by a couple of activating and functionalized reagents for efficient CO2 capture and selective CO2/CH4 separation
Li, Yao
Wang, Yage
Liu, Nan
Wang, Binbin
Dong, Rusong
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2023, 658
[47] Study on the adsorption of CH4, CO2 and various CH4/CO2 mixture gases on shale
Du, Xidong
Cheng, Yugang
Liu, Zhenjian
Hou, Zhenkun
Wu, Tengfei
Lei, Ruide
Shu, Couxian
ALEXANDRIA ENGINEERING JOURNAL, 2020, 59 (06) : 5165 - 5178
[48] Porous Carbon Nanotube Membranes for Separation of H2/CH4 and CO2/CH4 Mixtures
Bucior, Benjamin J.
Chen, De-Li
Liu, Jinchen
Johnson, J. Karl
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (49): : 25904 - 25910
[49] Effects of nitrogen and oxygen on electrochemical reduction of CO2 in nitrogen-doped carbon black
Zeng, Qingting
Yang, Guangxing
Chen, Jianhao
Zhang, Qiao
Liu, Zhiting
Qin, Binhao
Peng, Feng
CARBON, 2023, 202 : 1 - 11
[50] Sustainable nanoporous carbon for CO2, CH4, N2, H2 adsorption and CO2/CH4 and CO2/N2 separation
Park, Jaewoo
Attia, Nour F.
Jung, Minji
Lee, Myoung Eun
Lee, Kiyoung
Chung, Jaewoo
Oh, Hyunchul
ENERGY, 2018, 158 : 9 - 16

← 1 2 3 4 5 →