A 2-Iodobenzamide Catalyst for Oxidation of Alcohols at Room Temperature

被引：9

作者：

Yakura, Takayuki ^{[1
]}

Yamada, Akihiro ^{[1
]}

Noda, Narumi ^{[1
]}

Fujiwara, Tomoya ^{[1
]}

Nambu, Hisanori ^{[1
]}

机构：

[1] Toyama Univ, Grad Sch Med & Pharmaceut Sci, Sugitani, Toyama 9300194, Japan

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 3卷 / 04期

关键词：

alcohols; carbonyl compounds; hypervalent iodine; 2-iodobenzamide; oxidation; HYPERVALENT IODINE OXIDATION; POLYMER-SUPPORTED IBX; 4-IODOPHENOXYACETIC ACID; SECONDARY ALCOHOLS; 2-IODOXYBENZOIC ACID; IODOXYBENZOIC ACID; REAGENT; OXONE(R); DERIVATIVES; CONVERSION;

D O I：

10.1002/ajoc.201300279

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A 2-iodobenzamide catalyst for the oxidation of alcohols was developed. Reaction of alcohols with a catalytic amount of 2-iodobenzamide in the presence of oxone as a co-oxidant at room temperature gave the corresponding carbonyl compounds in excellent yields. Primary alcohols were directly converted into the corresponding carboxylic acids, whereas secondary alcohols were oxidized to ketones. A 2-iodobenzoic acid-type catalyst for alcohol oxidation at room temperature has not been reported before.

引用

页码：421 / 424

页数：4

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