Lithiated Primary Amine-A New Material for Hydrogen Storage

被引：14

作者：

Chen, Juner ^{[1
,2
]}

Wu, Hui ^{[3
,4
]}

Wu, Guotao ^{[1
]}

Xiong, Zhitao ^{[1
]}

Wang, Ruiming ^{[1
]}

Fan, Hongjun ^{[1
]}

Zhou, Wei ^{[3
,4
]}

Liu, Bin ^{[1
]}

Chua, Yongshen ^{[1
]}

Ju, Xiaohua ^{[1
]}

Chen, Ping ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA

[4] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 22期

关键词：

dehydrogenation; hydrogen storage; lithiated amines; organometallic chemistry; -elimination; OXIDATIVE DEHYDROGENATION; PINCER COMPLEXES; METAL; CATALYSTS; LITHIUM; DECOMPOSITION; MOLYBDENUM; ACTIVATION; MECHANISM; NITRILES;

D O I：

10.1002/chem.201402543

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile method for synthesizing crystalline lithiated amines by ball milling primary amines with LiH was developed. The lithiated amines exhibit an unprecedented endothermic dehydrogenation feature in the temperature range of 150-250 degrees C, which shows potential as a new type of hydrogen storage material. Structural analysis and mechanistic studies on lithiated ethylenediamine (Li(2)EDA) indicates that Li may mediate the dehydrogenation through an ,-LiH elimination mechanism, creating a more energy favorable pathway for the selective H-2 release.

引用

页码：6632 / 6635

页数：4

共 50 条

[41] Carbon nanofoam as a potential hydrogen storage material
Blinc, R.
Arcon, D.
Umek, P.
Apih, T.
Milia, F.
Rode, A. V.
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2007, 244 (11): : 4308 - 4310
[42] Ammonium phosphate as promised hydrogen storage material
Barakat, Nasser A. M.
Ahmed, Enas
Abdelkareem, Mohammad Ali
Farrag, T. E.
Al-Meer, Saeed
Al-Deyab, Salem
Elsaid, Khaled
Nassar, M. M.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (32) : 10103 - 10110
[43] Material factors in the decrepitation of hydrogen storage alloys
Suda, Takanori
Kobayashi, Ryouichi
Watanabe, Seiichi
Ohnuki, Somei
Takahashi, Heishitirou
Arashima, Hironobu
Kabutomori, Toshiki
Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals, 1999, 63 (05): : 601 - 604
[44] Aluminium hydride: a reversible material for hydrogen storage
Zidan, Ragaiy
Garcia-Diaz, Brenda L.
Fewox, Christopher S.
Stowe, Ashley C.
Gray, Joshua R.
Harter, Andrew G.
CHEMICAL COMMUNICATIONS, 2009, (25) : 3717 - 3719
[45] Hydrazine borane: A promising hydrogen storage material
Hügle, Thomas
Kühnel, Moritz F.
Lentz, Dieter
Journal of the American Chemical Society, 2009, 131 (21): : 7444 - 7446
[46] Improving Reproducibility in Hydrogen Storage Material Research
Broom, Darren P.
Hirscher, Michael
CHEMPHYSCHEM, 2021, 22 (21) : 2141 - 2157
[47] Carbon nanoscrolls: A promising material for hydrogen storage
Mpourmpakis, Giannis
Tylianakis, Emmanuel
Froudakis, George E.
NANO LETTERS, 2007, 7 (07) : 1893 - 1897
[48] Hydrazine Borane: A Promising Hydrogen Storage Material
Huegle, Thomas
Kuehnel, Moritz F.
Lentz, Dieter
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (21) : 7444 - 7446
[49] ZEOLITE AS MATERIAL FOR HYDROGEN STORAGE IN TRANSPORT APPLICATIONS
Kleperis, J.
Lesnicenoks, P.
Grinberga, L.
Chikvaidze, G.
Klavins, J.
LATVIAN JOURNAL OF PHYSICS AND TECHNICAL SCIENCES, 2013, 50 (03) : 59 - 64
[50] Comment on "Material-based hydrogen storage"
Drulis, H.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (03) : 1627 - 1628

← 1 2 3 4 5 →