The progress in the chemistry of N-acyliminium ions and their use in stereoselective organic synthesis

被引：25
|
作者：
Vinogradov, Maxim G. [1 ]
Turova, Olga V. [2 ]
Zlotin, Sergei G. [2 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Lab Fine Organ Synth, ZIOC RAS, Leninsky Prosp 47, Moscow 119991, Russia
[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Lab Fine Organ Synth, Leninsky Prosp 47, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL REVIEWS | 2017年 / 86卷 / 01期
基金：
俄罗斯科学基金会;
关键词：
IN-SITU GENERATION; DIASTEREOSELECTIVE CONSTRUCTION; MANNICH REACTIONS; FACILE SYNTHESIS; CYCLIZATION; ACID; THIOUREA; INDOLES; ACCESS; DERIVATIVES;
D O I：
10.1070/RCR4628
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The review summarizes data published in the last decade on the reactions of organic compounds involving N-acyliminium ions, including intramolecular arylation (cyclization), cross-coupling with nucleophiles and some other transformations to form new carbon carbon and carbon-heteroatom bonds. The stereo-and enantioselective versions of these reactions using chiral auxiliaries and asymmetric catalysts (organocatalysts) are considered. Examples of application of N-acyliminium ions for the synthesis of natural compounds and their analogues are presented. The bibliography includes 100 references.
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收藏
页码：1 / 17
页数：17
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