Facile formation of a μ[σ2,η3-C4H5], μ-hydrido dizirconium complex through multiple intra- and intermolecular C-H bond activations of an isobutyl group

被引：15

作者：

Keaton, RJ ^{[1
]}

Sita, LR ^{[1
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 21期

关键词：

D O I：

10.1021/om020469y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis of (eta(5)-C5Me5)Zr(i-Bu)(2)[N(t-Bu)C-(Me)N(Et)] (3) at 50 T in benzene ultimately produces, in high yield, the mu-hydrido dizirconium complex 6 that bears a novel mu-[sigma(2), eta(3)-C4H5] fragment arising from multiple intra- and intermolecular C-H bond activations of an isobutyl group.

引用

页码：4315 / 4317

页数：3

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