Facile formation of a μ[σ2,η3-C4H5], μ-hydrido dizirconium complex through multiple intra- and intermolecular C-H bond activations of an isobutyl group

被引：15
|
作者：
Keaton, RJ [1 ]
Sita, LR [1 ]
机构：
[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 21期
关键词：
D O I：
10.1021/om020469y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Thermolysis of (eta(5)-C5Me5)Zr(i-Bu)(2)[N(t-Bu)C-(Me)N(Et)] (3) at 50 T in benzene ultimately produces, in high yield, the mu-hydrido dizirconium complex 6 that bears a novel mu-[sigma(2), eta(3)-C4H5] fragment arising from multiple intra- and intermolecular C-H bond activations of an isobutyl group.
引用
收藏
页码：4315 / 4317
页数：3
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