Crystal structure and two-level supramolecular organization of glycinium triiodide

被引：18

作者：

Shestimerova, T. A. ^{[1
]}

Bykov, M. A. ^{[1
]}

Wei, Z. ^{[2
]}

Dikarev, E. V. ^{[2
]}

Shevelkov, A. V. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Bldg 3,1 Leninskie Gory, Moscow 119991, Russia

[2] SUNY Albany, Dept Chem, Albany, NY 12222 USA

来源：

RUSSIAN CHEMICAL BULLETIN | 2019年 / 68卷 / 08期

基金：

美国国家科学基金会; 俄罗斯科学基金会;

关键词：

polyiodides; crystal structure; supramolecular architecture; Raman spectroscopy; IODINE; POLYIODIDE; COMPLEXES; HYBRID;

D O I：

10.1007/s11172-019-2586-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Glycinium triiodide was synthesized and its crystal structure was determined. The crystal structure consists of alternating asymmetric triiodide anions characterized by Raman spectroscopy and glycinium cations. The cations and anions form dimers (GlyH)(2)(I-3)(2)via (N)H center dot center dot center dot O, (N)H center dot center dot center dot I, and (O)H center dot center dot center dot I hydrogen bonds. The dimers are further linked into chains by secondary I center dot center dot center dot I interactions between adjacent triiodide anions. The supramolecular structure of glycinium triiodide is discussed in comparison with polyiodides of various cations.

引用

页码：1520 / 1524

页数：5

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