Atmospheric pressure chemical ionization liquid chromatography mass spectrometry and its application to conservation: Analysis of triacylglycerols

被引:11
|
作者
Shibayama, N
Lomax, SQ
Sutherland, K
La Rie, ERD
机构
[1] Metropolitan Museum Art, New York, NY 10028 USA
[2] Natl Gallery Art, Sci Res Dept, Washington, DC 20565 USA
关键词
D O I
10.2307/1506655
中图分类号
K85 [文物考古];
学科分类号
0601 ;
摘要
Atmospheric pressure chemical ionization (APCI) is an interface used to couple liquid chromatography (LC) to mass spectrometry (MS). It is suitable for a variety of materials, and allows for LC flow rates of up to 2mLmin-1. Although an established technique, APCI LC/MS has received little attention in the analysis of artists' materials. This paper describes the application of the technique to two conservation related problems: analysis of a white exudate on a painting by Mark Rothko ('Number 7'), National Gallery of Art, Washington DC) and the analysis of components present in acetone (propanone) extracts of oil paint films.
引用
收藏
页码:253 / 268
页数:16
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