Synthesis and Aggregation of Double Hydrophilic Diblock Glycopolymers via Aqueous SET-LRP

被引：60
|
作者：
Zhang, Qiang [1 ]
Wilson, Paul [1 ,2 ]
Anastasaki, Athina [1 ]
McHale, Ronan [1 ]
Haddleton, David M. [1 ,2 ]
机构：
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
[2] Monash Univ, Monash Inst Pharmaceut Sci, Parkville, Vic 3052, Australia
来源：
ACS MACRO LETTERS | 2014年 / 3卷 / 05期
关键词：
LIVING RADICAL POLYMERIZATION; AMPHIPHILIC BLOCK-COPOLYMERS; FRAGMENTATION CHAIN TRANSFER; RAFT POLYMERIZATION; 2-(DIMETHYLAMINO)ETHYL METHACRYLATE; MULTIBLOCK COPOLYMERS; METHYL-METHACRYLATE; CLICK CHEMISTRY; VINYL-CHLORIDE; RECOGNITION;
D O I：
10.1021/mz5001724
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A chemically unprotected mannose-containing acrylate (ManA) monomer was synthesized and polymerized by Cu(0)-mediated radical polymerization in water (SET-LRP). One-pot block copolymerization was achieved upon addition of a solution of N-isopropylacrylamide (NIPAm) or diethylene glycol ethyl ether acrylate (DEGEEA) forming thermoresponsive double hydrophilic diblock glycopolymers which revealed self-assembly properties in aqueous solution forming well-defined, sugar-decorated nanoparticles.
引用
收藏
页码：491 / 495
页数：5
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