Functionalization of multi-walled carbon nanotubes by electrografting of polyacrylonitrile

被引:40
|
作者
Petrov, P [1 ]
Lou, XD [1 ]
Pagnoulle, C [1 ]
Jérôme, C [1 ]
Calberg, C [1 ]
Jérôme, R [1 ]
机构
[1] Univ Liege, CERM, B-4000 Cointe Ougree, Belgium
关键词
carbon nanotubes; dispersions; electrochemistry; electropolymerization; surfaces;
D O I
10.1002/marc.200400055
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Multi-walled carbon nanotubes (MWNTs) ha been successfully modified with polyacrylonitrile (PAN) a cathodic electrochemical process. The surface-modified MWNTs afforded are then dispersible in good solvents PAN, such as N,N-dimethylformamide (DMF). Collect from a dilute dispersion, these MWNTs are essentially disentangled, as confirmed by transmission electron microscopy (TEM) analysis. From the differential scanning calorimetry (DSC) traces for polyacrylonitrile and polyacrylonitrile-grafted MWNTs, the maximum grafting ratio is estimated at 0.28.
引用
收藏
页码:987 / 990
页数:4
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