Rh-catalyzed asymmetric hydrogenation of α-aryl imino esters:: An efficient enantioselective synthesis of aryl glycine derivatives

被引：115

作者：

Shang, Gao ^{[1
]}

Yang, Qin ^{[1
]}

Zhang, Xumu ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 38期

关键词：

amino acids; asymmetric catalysis; enantioselectivity; hydrogenation; reduction;

D O I：

10.1002/anie.200601540

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A highly enantioselective synthesis of aryl glycine derivatives from asymmetric hydrogenation was achieved by subjecting N-PMP-protected α-aryl imino esters to hydrogenation under Rh-bisphosphine catalysis (see scheme; PMP = para-methoxyphenyl, cod = cycloocta-1,5-diene). The PMP group could be easily removed for the preparation of enantiomerically pure aryl glycine derivatives. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6360 / 6362

页数：3

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