Industrial synthesis of reactive silicones: reaction mechanisms and processes

被引：55

作者：

Koehler, Theresia ^{[1
]}

Gutacker, Andrea ^{[2
]}

Mejia, Esteban ^{[3
]}

机构：

[1] Henkel Belgium NV, Nijverheidstr 7, B-2260 Westerlo, Belgium

[2] Henkel AG & Co KGaA, Henkelstr 67, D-40191 Dusseldorf, Germany

[3] Leibniz Inst Catalysis, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ORGANIC CHEMISTRY FRONTIERS | 2020年 / 7卷 / 24期

关键词：

RING-OPENING POLYMERIZATION; N-HETEROCYCLIC CARBENES; ANIONIC-POLYMERIZATION; CATIONIC-POLYMERIZATION; POLY(DIMETHYLSILOXANE) MACROMONOMERS; ORGANIC DERIVATIVES; HEXAMETHYLCYCLOTRISILOXANE; POLYDIMETHYLSILOXANE; INITIATOR; SILOXANE;

D O I：

10.1039/d0qo01075h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silicones and silicone rubbers are ubiquitous in our daily lives, being used in a broad range of applications ranging from consumer products and adhesives to medicinal and electronic devices. The chemistry and synthesis of these versatile materials have been reviewed so many times that it is difficult to have a comprehensive overview. Hence, with this tutorial review we aim to provide a concise account of the most important reactions and industrial processes to furnish silicones, focusing specially on reactive silicones, specifically in telechelic OH-terminated polysiloxanes, which represent one of the most relevant members of this important materials family.

引用

页码：4108 / 4120

页数：13

共 50 条

[21] NOVEL SYNTHESIS OF SULFONATED SILICONES
LIU, JK
WNEK, GE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 609 - POLY
[22] Printing of reactive silicones for surface modification of textile material
Bechtold, Thomas (Thomas.Bechtold@uibk.ac.at), 1600, John Wiley and Sons Inc (132):
[23] Reaction mechanisms of transition metal catalyzed processes
Boehme, Christian
Dapprich, Stefan
Deubel, Dirk
Pidun, Ulrich
Stahl, Martin
Stegmann, Ralf
Frenking, Gernot
ACS Symposium Series, 721 : 114 - 127
[24] MECHANISMS OF ELEMENTARY REACTION PROCESSES OF BIOLOGICAL SIGNIFICANCE
HAGUE, DN
CHEMISTRY IN BRITAIN, 1974, 10 (07) : 261 - 262
[25] REACTION PATH SYNTHESIS IN INDUSTRIAL CHEMISTRY
AGNIHOTRI, RB
MOTARD, RL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (SEP): : 80 - 80
[26] MECHANISMS OF REACTION OF REACTIVE DYES WITH CELLULOSIC AND OTHER FIBRES
STAMM, OA
JOURNAL OF THE SOCIETY OF DYERS AND COLOURISTS, 1964, 80 (08): : 416 - 422
[27] UNIMOLECULAR REACTION-MECHANISMS - THE ROLE OF REACTIVE INTERMEDIATES
GRUTZMACHER, HF
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1992, 118 : 825 - 855
[28] Printing of reactive silicones for surface modification of textile material
Turalija, Marina
Bechtold, Thomas
JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (39)
[29] Design and synthesis of feasible reactive distillation processes
Giessler, S
Danilov, RY
Pisarenko, RY
Serafimov, LA
Hasebe, S
Hashimoto, I
COMPUTERS & CHEMICAL ENGINEERING, 1999, 23 : S811 - S814
[30] A systematic matrix-based method for synthesis and optimization of Reaction/Distillation processes including Reactive Distillation
Nezhadfard, Mahya
Tamuzi, Amin
Khalili-Garakani, Amirhossein
Kasiri, Norollah
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2022, 186 : 206 - 228

← 1 2 3 4 5 →