[4+2] Annulation of Donor-Acceptor Cyclopropanes with Acetylenes Using 1,2-Zwitterionic Reactivity

被引：51

作者：

Novikov, Roman A. ^{[1
,2
]}

Tarasova, Anna V. ^{[1
]}

Denisov, Dmitry A. ^{[1
]}

Borisov, Denis D. ^{[1
]}

Korolev, Victor A. ^{[1
]}

Timofeev, Vladimir P. ^{[2
]}

Tomilov, Yury V. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia

[2] Russian Acad Sci, Engelhardt Inst Mol Biol, 32 Vavilov St, Moscow 119991, Russia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 05期

基金：

俄罗斯科学基金会;

关键词：

SUBSTITUTED NAPHTHALENES; REGIOSELECTIVE SYNTHESIS; MEDIATED DIMERIZATION; GRIGNARD-REAGENTS; DERIVATIVES; ACID; LEWIS; DIHYDRONAPHTHALENES; NITROSOARENES; INHIBITORS;

D O I：

10.1021/acs.joc.7b00209

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new process for the [4 + 2] annulation of donor-acceptor cyclopropanes with acetylenes under the effect of anhydrous GaCl3 using 1,2-zwitterion reactivity was elaborated. The reaction opens access to substituted dihydronaphthalenes, naphthalenes, and other fused carbocycles. The direction of the reaction can be efficiently controlled by temperature.

引用

页码：2724 / 2738

页数：15

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