Synthesis, structure and magnetic properties of two new coordination polymers with carboxylate-substituted benzoimidazole ligands

被引：13
|
作者：
Hu BoWen [1 ]
Zhao JiongPeng [1 ]
Yang Qian [1 ]
Zhang XiaoFeng [1 ]
Bu XianHe [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
SCIENCE IN CHINA SERIES B-CHEMISTRY | 2009年 / 52卷 / 09期
基金：
中国国家自然科学基金;
关键词：
carboxylate-substituted benzoimidazole; formate; magnetic property; synthesis; structure; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURES; COMPLEXES; CHAINS; ACID;
D O I：
10.1007/s11426-009-0215-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This paper reports two new coordination polymers formed by carboxylate-substituted benzoimidazole and formate ligands: [Mn(L)center dot(HCO2)] (n) (1) and [Co(L)center dot(HCO2)] (n) (2) (L = benzoimidazol-1-yl-acetate). Complexes 1 and 2 are isomorphous and adopt a new 3,6-connected three-nodal topology showing interesting magnetic properties: spin canted antiferromagnetism for Mn-II complex 1, but simple antiferromagnetic coupling for Co-II complex 2.
引用
收藏
页码：1451 / 1455
页数：5
相关论文
共 50 条
  • [21] Two 3D Coordination Polymers with New Topology Based on Mixed Ligands: Synthesis, Structure, and Photoluminescence Properties
    Tao Wang
    Jingyuan Ji
    Shengjun Deng
    Bang Li
    Weiming Xiao
    Ning Zhang
    Journal of Inorganic and Organometallic Polymers and Materials, 2018, 28 : 1439 - 1445
  • [22] Synthesis, structure, topology and magnetic properties of new coordination polymers based on 5(-Br/-COOH)-substituted nicotinic acid
    Nandi, Goutam
    Thakuria, Ranjit
    Titi, Hatem M.
    Patra, Ranjan
    Goldberg, Israel
    CRYSTENGCOMM, 2014, 16 (24) : 5244 - 5256
  • [23] Two Coordination Polymers Based on Carboxylate Ligands and Fe(II): Preparation, Structural Characterization and Properties
    Huang Yan-Ju
    Du Gang
    Hao Xiang-Rong
    Zhang Tie-Ying
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2016, 32 (02) : 313 - 319
  • [24] Two New Cd(II) Coordination Polymers Based on Triazolyl Derivative and Different Carboxylate Ligands, Their Crystal Structures and Properties
    Wang, Y. F.
    Zhang, S. Q.
    Feng, Y. X.
    Wang, L. Y.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (08) : 1566 - 1571
  • [25] Two New Cd(II) Coordination Polymers Based on Triazolyl Derivative and Different Carboxylate Ligands, Their Crystal Structures and Properties
    Y. F. Wang
    S. Q. Zhang
    Y. X. Feng
    L. Y. Wang
    Russian Journal of General Chemistry, 2021, 91 : 1566 - 1571
  • [26] Three-Dimensional Metal Azide Coordination Polymers with Amino Carboxylate Coligands: Synthesis, Structure, and Magnetic Properties
    Chen, Zi-Lu
    Jiang, Chun-Fang
    Yan, Wei-Hong
    Liang, Fu-Pei
    Batten, Stuart R.
    INORGANIC CHEMISTRY, 2009, 48 (11) : 4674 - 4684
  • [27] Two novel europium coordination polymers based on fluorine substituted and similar carboxylate ligands: Syntheses, structures and luminescence
    Feng, Xun
    Sun, Yi-Ling
    Li, Rong-Fang
    Zhang, Tian
    Guo, Nan
    Wang, Li-Ya
    INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 73 : 190 - 195
  • [28] Hydrothermal synthesis of two new zinc coordination polymers with mixed ligands
    Wu, CD
    Lu, CZ
    Wu, DM
    Zhuang, HH
    Huang, JS
    INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (10) : 561 - 564
  • [29] Synthesis, structure, and characterization of two 1-D homometallic coordination polymers based on carboxylate-functionlized salen ligands
    Hao, Lina
    Lu, Ying
    He, Zhenzhen
    Lan, Qing
    Wang, Enbo
    JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (15) : 2682 - 2690
  • [30] Synthesis and crystal structure of two new lead(II) coordination polymers with substituted 2,2′-bipyridine ligands with dicyanamide and nitrate as co-ligands
    Marandi, Farzin
    Amoopour, Fariba
    Pantenburg, Ingo
    Meyer, Gerd
    JOURNAL OF MOLECULAR STRUCTURE, 2010, 973 (1-3) : 124 - 129
12345