Epoxy Resin Composite Based on Functional Hybrid Fillers

被引：37
|
作者：
Oleksy, Mariusz [1 ]
Szwarc-Rzepka, Karolina [2 ]
Heneczkowski, Maciej [1 ]
Oliwa, Rafal [1 ]
Jesionowski, Teofil [2 ]
机构：
[1] Rzeszow Univ Technol, Fac Chem, PL-35959 Rzeszow, Poland
[2] Poznan Univ Tech, Inst Chem Technol & Engn, Fac Chem Technol, PL-60965 Poznan, Poland
来源：
MATERIALS | 2014年 / 7卷 / 08期
关键词：
epoxy resin; hybrid polymer composites; polyhedral oligomeric silsesquioxane (POSS); modified bentonite; modified silica; mechanical properties; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; THERMAL-PROPERTIES; AMORPHOUS SILICA; MECHANICAL-PROPERTIES; PS NANOCOMPOSITES; POSS; BEHAVIOR; BENTONITES; AMMONIUM;
D O I：
10.3390/ma7086064
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A study was carried out involving the filling of epoxy resin (EP) with bentonites and silica modified with polyhedral oligomeric silsesquioxane (POSS). The method of homogenization and the type of filler affect the functional and canceling properties of the composites was determined. The filler content ranged from 1.5% to 4.5% by mass. The basic mechanical properties of the hybrid composites were found to improve, and, in particular, there was an increase in tensile strength by 44%, and in Charpy impact strength by 93%. The developed hybrid composites had characteristics typical of polymer nanocomposites modified by clays, with a fine plate morphology of brittle fractures observed by SEM, absence of a plate separation peak in Wide Angles X-ray Scattering (WAXS) curves, and an exfoliated structure observed by TEM.
引用
收藏
页码：6064 / 6091
页数：28
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