Oxygen exchange materials for solar thermochemical splitting of H2O and CO2: a review

被引：312
|
作者：
Scheffe, Jonathan R. [1 ]
Steinfeld, Aldo [1 ,2 ]
机构：
[1] ETH, Dept Mech & Proc Engn, CH-8092 Zurich, Switzerland
[2] Paul Scherrer Inst, Solar Technol Lab, CH-5232 Villigen, Switzerland
来源：
MATERIALS TODAY | 2014年 / 17卷 / 07期
基金：
欧洲研究理事会;
关键词：
HYDROGEN-PRODUCTION; IRON-OXIDE; THERMODYNAMIC ANALYSIS; CATION DIFFUSION; DEFECT STRUCTURE; WATER; TEMPERATURE; CYCLE; CERIA; NONSTOICHIOMETRY;
D O I：
10.1016/j.mattod.2014.04.025
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
This review summarizes state of the art metal oxide materials used in two-step thermochemical redox cycles for the production of H-2 and CO from H2O and CO2 using concentrated solar energy. Advantages and disadvantages of both stoichiometric (e. g. iron oxide based cycles) and nonstoichiometric (e. g. ceria based cycles) materials are discussed in the context of thermodynamics, chemical kinetics, and material stability. Finally, a perspective aimed at future materials development and requirements necessary for advances of process efficiencies is discussed.
引用
收藏
页码：341 / 348
页数：8
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