Hydrothermal syntheses, and crystal structures of new lanthanide coordination polymers with nitrilotriacetic acid

被引：7
|
作者：
Yu, Liang-Cai
Chen, Zhen-Feng [1 ]
Liu, Yan-Cheng
Liang, Hong
Zhou, Chun-Shan
Zhang, Yong
机构：
[1] Guangxi Normal Univ, Coll Chem & Chem Engn, Guilin 541004, Peoples R China
[2] Cent S Univ, Coll Chem & Chem Engn, Changsha 410012, Peoples R China
[3] Suzhou Univ, Coll Chem & Chem Engn, Suzhou 215006, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2006年 / 59卷 / 11期
基金：
中国国家自然科学基金;
关键词：
lanthanide complex; nitrilotriacetic acid; crystal structure;
D O I：
10.1080/00958970500470741
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrothermal reactions of Nd(ClO4)(3)center dot 6H(2)O, Gd(ClO4)(3)center dot 6H(2)O and Er2O3 with H(3)NTA (nitrilotriacetic acid) afford three new lanthanide coordination polymers, {[Nd(NTA)(H2O)]center dot 2H(2)O}(n) (1), {[Gd(NTA)(H2O)]center dot 2H(2)O}(n) (2) and {[Er(NTA)(H2O)]center dot H2O} n (3), characterized by elemental analysis and IR spectroscopy. X-ray single crystal structural analyses showed that 1 and 2 are an isomorphous 2D-layered framework containing the nine-coordinated Nd(III) (or Gd(III)), and woven into a 3D suprastructure by interlayer hydrogen bonding while 3 is a 3D structure with eight-coordinate Er(III).
引用
收藏
页码：1203 / 1211
页数：9
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