AgPd nanoparticles supported on MIL-101 as high performance catalysts for catalytic dehydrogenation of formic acid

被引：108

作者：

Dai, Hongmei ^{[1
]}

Cao, Nan ^{[1
]}

Yang, Lan ^{[1
]}

Su, Jun ^{[3
]}

Luo, Wei ^{[1
,2
]}

Cheng, Gongzhen ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China

[2] Wuhan Univ, Suzhou Inst, Suzhou 215123, Jiangsu, Peoples R China

[3] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430072, Hubei, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 29期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; HYDROGEN-STORAGE MATERIALS; EFFICIENT CATALYST; PD NANOPARTICLES; AMMONIA-BORANE; SELECTIVE DECOMPOSITION; SYNERGISTIC CATALYSIS; ALLOY NANOPARTICLES; RUTHENIUM COMPLEX; ROOM-TEMPERATURE;

D O I：

10.1039/c4ta02066a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bimetallic AgPd nanoparticles were successfully immobilized into the metal-organic frameworks (MIL-101), and tested for their catalytic dehydrogenation of formic acid. These catalysts were composition dependent for the catalytic activity. Among all the AgPd@MIL-101 catalysts tested, the Ag20Pd80@MIL-101 catalyst exhibits the highest catalytic activity for the conversion of formic acid to high-quality hydrogen at 80 degrees C with a TOF value of 848 h(-1), which is among the highest values reported at 80 degrees C.

引用

页码：11060 / 11064

页数：5

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