Facile synthesis and structures of infinite one-dimensional silver(I) coordination polymers

被引：15
|
作者：
Pickering, AL [1 ]
Cooper, GJT [1 ]
Long, DL [1 ]
Cronin, L [1 ]
机构：
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
来源：
POLYHEDRON | 2004年 / 23卷 / 12期
基金：
英国工程与自然科学研究理事会;
关键词：
one-dimensional; silver(I); aliphatic amino ligands; coordination polymers; tubes; topology; supramolecular chemistry; self assembly; nanotubes;
D O I：
10.1016/j.poly.2004.06.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of the isolated, infinite tubular coordination polymers {[Ag(cis-tach)]ClO4}(infinity) (1), {[Ag(transtach)]ClO4}(infinity) (2) and {[Ag(cis-tach)]BF4}(infinity) (3) has been achieved with the isomers cis, cis-1,3,5-triaminocyclohexane and cis,trans-1,3,5-triaminocyclohexane. Each new material has been fully characterized by single crystal X-ray diffraction, NMR, IR and elemental analysis. Compounds 1-3 form definite channels by the trigonal planar coordination of silver(l) metal centres to rigid, aliphatic triamino ligands, forming 4(2) (.) 6 topological networks. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2075 / 2079
页数：5
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