Green Oxidative Degradation of Methyl Orange with Copper(II) Schiff Base Complexes as Photo-Fenton-Like Catalysts

被引：20
|
作者：
Fei, Bao-Li [1 ,2 ]
Yan, Qing-Ling [1 ]
Wang, Jiang-Hong [1 ]
Liu, Qing-Bo [3 ]
Long, Jian-Ying [3 ]
Li, Yang-Guang [4 ]
Shao, Kui-Zhan [4 ]
Su, Zhong-Min [4 ]
Sun, Wei-Yin [2 ]
机构：
[1] Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[3] Nanjing Forestry Univ, Coll Sci, Nanjing 210037, Jiangsu, Peoples R China
[4] NE Normal Univ, Inst Funct Mat Chem, Fac Chem, Changchun 130024, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 10期
关键词：
HYDROGEN-PEROXIDE; DECOLORIZATION; ACTIVATION; SYSTEMS; METAL; MINERALIZATION; DIOXYGEN; KINETICS; CRYSTAL; DYES;
D O I：
10.1002/zaac.201300562
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two copper(II) complexes, namely [Cu(HL)Cl] (1) and [Cu(HL)Br](2), where HL is the multidentate Schiffbase N-[(2-oxy-acetate)benzyl]-2-aminothanol, were synthesized and fully characterized. The Cu-II ions in 1 and 2 are pentacoordinate and the coordination arrangement is best described as distorted square-pyramidal. The degradation of methyl orange (MO) was investigated using 1 and 2 as homogeneous photo-Fenton-like catalysts. 1 and 2 exhibited similar catalytic activity at neutral pH. The results suggest that they have advantages on catalyzing efficient degradation of organic dye through photo-Fenton-like reaction.
引用
收藏
页码：2035 / 2040
页数：6
相关论文
共 50 条
  • [41] Fenton-like degradation of methyl orange by alumina-supported Cu-Co catalysts at neutral pH: Optimization by the Taguchi method
    Juang, Yayun
    Jehng, Jih-Mirn
    ENERGY & ENVIRONMENT, 2023,
  • [42] Green approach to synthesize, spectral investigation and biological applications of potentially active ternary schiff base copper(II) complexes
    Karthik, A. Dinesh
    Shakila, D.
    Geetha, K.
    Muthuvel, I.
    MATERIALS TODAY-PROCEEDINGS, 2021, 43 : 2389 - 2396
  • [43] Statistical Optimization and Modeling Approach for Fenton-like Discoloration of Methyl Orange using Green Zero-valent Iron Nanoparticle Catalysts
    Chowdhury, Sujan
    Al-Mamun, Abdullah
    Zulfiqar, Muhammad
    Alam, M. M.
    Rahman, Mohammed M.
    CHEMISTRYSELECT, 2022, 7 (05):
  • [44] Application of UV-A light Operating Photoreactor for Green Degradation of Direct Blue 15 through the Photo-Fenton-like process: Effects and Box-Behnken Optimization
    Mahmoud, Zainab A.
    Atyia, Mohammed A.
    Hassan, Ahmed K.
    EGYPTIAN JOURNAL OF CHEMISTRY, 2023, 66 (11): : 77 - 91
  • [45] Copper/carbon composites from waste printed circuit boards as catalysts for Fenton-like degradation of Acid Orange 7 enhanced by ultrasound
    Wang, Chong-Qing
    Jiang, Xiao-Yan
    Huang, Rong
    Cao, Yi-Jun
    Xu, Jing
    Han, Yi-Fan
    AICHE JOURNAL, 2019, 65 (04) : 1234 - 1244
  • [46] Ruthenium(II) complexes of Schiff base derived from cycloalkylamines as pre-catalysts for ROMP of norbornene and ATRP of methyl methacrylate
    Afonso, Maria Beatriz A.
    Cruz, Thais R.
    Silva, Yan F.
    Pereira, Joao Clecio A.
    Machado, Antonio E. H.
    Goi, Beatriz E.
    Lima-Neto, Benedito S.
    Carvalho-, Valdemiro P., Jr.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 851 : 225 - 234
  • [47] Copper(II) complexes with tridentate Schiff base-like ligands: solid state and solution structures and anticancer activity
    Dankhoff, Katja
    Gold, Madeleine
    Kober, Luisa
    Schmitt, Florian
    Pfeifer, Lena
    Duerrmann, Andreas
    Kostrhunova, Hana
    Rothemund, Matthias
    Brabec, Viktor
    Schobert, Rainer
    Weber, Birgit
    DALTON TRANSACTIONS, 2019, 48 (40) : 15220 - 15230
  • [48] Copper (II) and Palladium (II) Schiff-Base Complexes as Homogeneous and Heterogeneous Catalyst for Efficient α-Methyl Oxidation Reaction: Experimental and DFT Approaches
    Lashanizadegan, Maryam
    Ghiasi, Mina
    Mirzazadeh, Hoda
    Ferizhandi, Azam N.
    CHEMISTRYSELECT, 2021, 6 (17): : 4074 - 4082
  • [49] Oxindole-Schiff base copper(II) complexes interactions with human serum albumin: Spectroscopic, oxidative damage, and computational studies
    da Silveira, Vivian Chagas
    Caramori, Giovanni Finoto
    Abbott, Mariana Pedrinha
    Goncalves, Marcos Brown
    Petrilli, Helena Maria
    da Costa Ferreira, Ana Maria
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2009, 103 (10) : 1331 - 1341
  • [50] Fenton-like oxidative degradation of Orange G dye and binary dye mixtures using Oxone® activated with cobalt-doped alumina catalysts
    Marinovic, Sanja R.
    Mudrinic, Tihana M.
    Ajdukovic, Marija J.
    Jovic-Jovicic, Natasa P.
    Nikolova, Dimitrinka A.
    Bankovic, Predrag T.
    Novakovic, Tatjana B.
    HEMIJSKA INDUSTRIJA, 2024, 78 (04) : 359 - 370
12345