Fabrication of Rare-Earth Metals by Metallothermic Reduction: Thermodynamic Modeling and Practical Realization

被引：4

作者：

Ivanov, V. A. ^{[1
]}

Dedyukhin, A. S. ^{[1
]}

Polovov, I. B. ^{[1
]}

Volkovich, V. A. ^{[1
]}

Rebrin, O. I. ^{[1
]}

机构：

[1] Ural Fed Univ, 19 Mira St, Ekaterinburg 620002, Russia

来源：

PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2018) | 2018年 / 2015卷

关键词：

D O I：

10.1063/1.5055106

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The thermodynamics of metallothermic reduction of rare earths was analyzed with different reductants and initial starting compounds. Alkali metals and calcium were found as the most suitable reagents for reducing rare earth fluorides. Thermodynamic calculations showed the advantages of lithium as the reducing agent. Processes of metallothermic reduction of neodymium, lanthanum, and cerium fluorides by lithium metal were studied on a semi-industrial scale.

引用

页数：7

共 50 条

[21] MAGNETISM OF RARE-EARTH METALS
LEMAIRE, R
PIERRE, J
REVUE DE CHIMIE MINERALE, 1973, 10 (1-2): : 273 - 290
[22] FLUORINATION OF RARE-EARTH METALS
RAKOV, EG
YAGODIN, GA
ZAGORETS, VP
ANDREEV, IY
GONCHAROV, VI
ZHURNAL NEORGANICHESKOI KHIMII, 1979, 24 (04): : 857 - 859
[23] TRANSFORMATIONS IN RARE-EARTH METALS
ALTSTETTER, CJ
METALLURGICAL TRANSACTIONS, 1973, 4 (12): : 2723 - 2730
[24] Calculations of the thermodynamic properties of rare-earth metal ferrites doped with alkaline-earth metals
Oskembekov, IM
Kasenov, BK
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2002, 76 (12): : 1930 - 1932
[25] Thermodynamic of interaction of rare-earth metals with d-metals. The scandium-iron system
Goncharuk, L.V.
Sidorko, V.R.
Poroshkovaya Metallurgiya, 2001, (7-8): : 54 - 62
[26] Thermodynamic characteristics of rare-earth element and its application in metals matrix composites
Cui, CX
Wu, RJ
Wang, HW
RARE METAL MATERIALS AND ENGINEERING, 1997, 26 (03) : 53 - 58
[27] THERMODYNAMIC PREDICTION OF DISTRIBUTION COEFFICIENTS FOR THE SOLVENT-EXTRACTION OF RARE-EARTH METALS
HAN, KS
TOZAWA, K
JOURNAL OF METALS, 1988, 40 (11): : 33 - 33
[28] Thermodynamic Characteristics of Rare-Earth Element and Its Application in Metals Matrix Composites
Cui, Chunxiang
Wu, Renjie
Wang, Haowei
Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering, 1997, 26 (03): : 57 - 58
[29] Thermodynamic Consideration of the Direct Removal of Oxygen from Titanium by Utilizing Metallothermic Reduction of Rare Earth Metal Halides
Okabe, Toru H.
Kamimura, Gen
Ouchi, Takanari
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2024, 55 (05): : 4015 - 4026
[30] REDUCTION OF AROMATIC KETONES BY SOME RARE-EARTH METALS IN ETHER - REVERSIBILITY OF THE REDUCTION STEPS
OLIVIER, H
CHAUVIN, Y
SAUSSINE, L
TETRAHEDRON, 1989, 45 (01) : 165 - 169

← 1 2 3 4 5 →