Peculiarities of formation of phase composition, porous structure, and catalytic properties of tungsten oxide-based macroporous materials fabricated by sol-gel synthesis

被引：7
|
作者：
Papynov, Evgeniy Konstantinovich [1 ,2 ]
Mayorov, Vitaliy Yurevich [1 ]
Palamarchuk, Marina Sergeevna [1 ]
Avramenko, Valentin Aleksandrovich [1 ,2 ]
机构：
[1] Russian Acad Sci, Inst Chem, Far East Branch, Vladivostok 690022, Russia
[2] Far Eastern Fed Univ, Sch Nat Sci, Vladivostok 690091, Russia
来源：
MATERIALS CHARACTERIZATION | 2014年 / 88卷
关键词：
Nanostructures; Oxides; Sol-gel synthesis; Surface properties; Phase transition; OXIDATION; ORGANIZATION; SURFACTANT; WO3;
D O I：
10.1016/j.matchar.2013.12.003
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The method of template sol-gel synthesis of tungsten oxide-based macroporous materials using 'core-shell' latex particles as colloid templates is described. The chemical composition and structural characteristics of the synthesized macroporous oxide systems have been investigated. The peculiarities of formation of material phase composition and macroporous structure under different template thermal destruction conditions have been revealed. An optimal method of a targeted synthesis of the crystalline tungsten(VI) oxide having a defect-free macroporous structure (average pore size 160 nm) and efficient catalytic properties under organic liquid phase oxidation conditions has been suggested. The prospects of the fabricated material application as catalysts of hydrothermal oxidation of radionuclide organic complexes at radioactive waste decontamination have been demonstrated. (C) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码：42 / 51
页数：10
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