Anion-controlled π-stacks of (ethylenediamine-N,N′)(1,10-phenanthroline-N,N′)-platinum(II)

被引：15

作者：

Kato, M ^{[1
]}

Takahashi, J

机构：

[1] Nara Womens Univ, Grad Sch Human Culture, Dept Mat Sci, Nara 6308506, Japan

[2] Japan Sci & Technol Corp, State & Informat PRESTO, Kawahguchi 3320012, Japan

[3] Nara Womens Univ, Grad Sch Human Culture, Dept Chem, Nara 6308506, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270199008859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two salts of (ethylenediamine-N,N')(1,10-phenanthroline-N,N') platinum(II), namely the dichloride dihydrate, [Pt(C2H8N2)(C12H8N2)]Cl-2.2H(2)O, (I), and the bis(hexafluorophosphate), [Pt(C2H8N2)(C12H8N2)] (PF6)(2), (II), have pi-phenanthroline-stacked structures. The interplanar spacings of the pi-pi stacks, however, are quite different in the two salts, being 3.38 (1) and 3.40(1) Angstrom for (I), and 3.60(5) and 3.56(5) Angstrom for (II), These are controlled by the anions located on the aliphatic sites.

引用

页码：1809 / 1812

页数：4

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