Anion-controlled π-stacks of (ethylenediamine-N,N′)(1,10-phenanthroline-N,N′)-platinum(II)

被引：15
|
作者：
Kato, M [1 ]
Takahashi, J
机构：
[1] Nara Womens Univ, Grad Sch Human Culture, Dept Mat Sci, Nara 6308506, Japan
[2] Japan Sci & Technol Corp, State & Informat PRESTO, Kawahguchi 3320012, Japan
[3] Nara Womens Univ, Grad Sch Human Culture, Dept Chem, Nara 6308506, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270199008859
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two salts of (ethylenediamine-N,N')(1,10-phenanthroline-N,N') platinum(II), namely the dichloride dihydrate, [Pt(C2H8N2)(C12H8N2)]Cl-2.2H(2)O, (I), and the bis(hexafluorophosphate), [Pt(C2H8N2)(C12H8N2)] (PF6)(2), (II), have pi-phenanthroline-stacked structures. The interplanar spacings of the pi-pi stacks, however, are quite different in the two salts, being 3.38 (1) and 3.40(1) Angstrom for (I), and 3.60(5) and 3.56(5) Angstrom for (II), These are controlled by the anions located on the aliphatic sites.
引用
收藏
页码：1809 / 1812
页数：4
相关论文
共 50 条
  • [1] Anion-controlled π-stacks of (ethylene-diamine-N,N prime )(1,10-phenanthroline-N,N prime )-platinum(II)
    Kato, Masako
    Takahashi, Junko
    Acta Crystallographica, Section C: Crystal Structure Communications, 1999, 55 (11): : 1809 - 1812
  • [2] Bis(1,10-phenanthroline-N,N′)copper(II) tetrathionate and tris(1,10-phenanthroline-N,N′)copper(II) tetrathionate pentahydrate
    Freire, E
    Baggio, S
    Baggio, R
    Garland, MT
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 464 - 468
  • [3] Diazidobis(1,10-phenanthroline-N,N′)-manganese(II)
    Shen, Z
    Zuo, JL
    Chinnakali, K
    Fun, HK
    You, XZ
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 901 - 903
  • [4] 1,10-PHENANTHROLINE-N,N'-DIOXIDE
    GILLARD, RD
    INORGANICA CHIMICA ACTA, 1989, 156 (02) : 155 - 155
  • [5] Bis(1,10-phenanthroline-N,N prime )copper(II) tetrathionate and tris(1,10-phenanthroline-N,N prime )copper(II) tetrathionate pentahydrate
    Freire, Eleonora
    Baggio, Sergio
    Baggio, Ricardo
    Garland, Maria Teresa
    Acta Crystallographica, Section C: Crystal Structure Communications, 1998, 54 (pt 4): : 464 - 468
  • [6] Tetraapua(1,10-phenanthroline-N,N′)-manganese(II) dinitrate
    Wang, WG
    Ma, CB
    Chen, F
    Chen, CG
    Liu, QT
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M908 - M910
  • [7] Cis-diaquabis(1,10-phenanthroline-N,N')zinc(II) (1,10-phenanthroline-N,N')bis(thiosulfato-S)zincate(II) monohydrate
    Baggio, R
    Baggio, S
    Pardo, MI
    Garland, MT
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1996, 52 : 820 - 823
  • [8] NONEXISTENCE OF 1,10-PHENANTHROLINE-N,N'-DIOXIDE
    GILLARD, RD
    INORGANICA CHIMICA ACTA-LETTERS, 1981, 53 (04): : L173 - L173
  • [9] (Dimethyl sulfoxide-S)methyl(1,10-phenanthroline-N,N')platinum(II) hexafluorophosphate
    Bruno, G
    Nicolo, F
    Scopelliti, R
    Arena, G
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1996, 52 : 827 - 829
  • [10] Tris(1,10-phenanthroline-N,N′)iron(II) dithiocyanate trihydrate
    Hoshina, G
    Ohba, S
    Tsuchiya, N
    Isobe, T
    Senna, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : e191 - e192
12345