New electron-transfer complexes of the [M-N2S2] type of Ni(II), Pd(II) and Pt(II) with bidentate ligands of the naphthoquinone series.

被引:0
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作者
Muresan, V [1 ]
Sbîrna, S
Lepadatu, C
Sbîrna, LS
Muresan, N
机构
[1] Univ Craiova, Fac Chem, Calea Bucuresti 165, Romania
[2] Aircraft SA, Dept Res & Dev, Craiova, Romania
[3] Romanian Acad, Inst Phys Chem, Bucharest, Romania
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O6 [化学];
学科分类号
0703 ;
摘要
The paper reports the study of the structure of some new electron-transfer complexes of the [M-N2S2] type of Ni(II), Pd(II) and Pt(II) with bidentate ligands of the naphthoquinone series by using IR, visible, UV and ESR spectra, conductometric and polarograpbic data. A quanto-mechanical interpretation of the electronic transitions for the free and coordinated ligand has been performed in order to get information on the coordination of the heteroatoms to the M(II) using the EHT-MO approach.
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页码:447 / 456
页数:10
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