Fabrication and electrical properties of YSZ thin-film electrolyte spin-coated on porous La0.6Sr0.4Co0.2Fe0.8O3 substrate from polymeric precursor solution

被引:1
|
作者
Wang, SQ
Awano, M
Maeda, K
机构
[1] FCRA, Synergy Ceram Lab, Moriyama Ku, Nagoya, Aichi 4638687, Japan
[2] AIST, Synergy Mat Res Ctr, Moriyama Ku, Nagoya, Aichi 4638687, Japan
关键词
YSZ; Ce09Gd01O1 95 (CGO); La(06)Sr(04)Co(02)Fe(08)O3(LSCF); spin coating; polymeric precursor solution; thin-film electrolyte; cell impedance;
D O I
10.2109/jcersj.110.780
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Deposition of dense 8 mol% Y2O3-stabilized ZrO2 (YSZ) electrolyte thin-films with and without Ce0.9Gd0.1O1.95 (CGO) interlayer by spin coating of polymeric precursor solutions on a porous La0.6Sr0.4Co0.2 Fe0.8O3 (LSCF) substrate and the electrical properties of the constructed thin-film cell were investigated. Anisotropic crystal growth in the YSZ thin films annealed at 1150degreesC was confirmed by XRD and SEM. The high-temperature chemical reaction between YSZ and LSCF was depressed by coating a CGO interlayer on the porous LSCF substrate before coating YSZ thin film. The impedance measurements of the electrochemical cell constructed by the LSCF electrode-supported YSZ thin-film electrolyte with CGO interlayer showed a lower electrode reaction resistance.
引用
收藏
页码:780 / 783
页数:4
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